137618-77-0

Basic information

• Product Name: C₂₇H₂₅N₄OP
• CAS NO: 137618-77-0
• Molecular Weight: 452.495
• Mol File: 137618-77-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₂₅N₄OP(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₂₅N₄OP(137618-77-0)
• EPA Substance Registry System: C₂₇H₂₅N₄OP(137618-77-0)

Safety Data

• Hazardous Substances Data: 137618-77-0(Hazardous Substances Data)

Upstream product

• 14619-80-8 9,10-dihydro-9(dicyanomethylene)phenanthrene-10-one 
• 6143-71-1 bis(dimethylamino)phenyl phosphine 

Relevant articles and documents

THE BEHAVIOUR OF PHENANTHRENEQUINONE DERIVATIVES TOWARDS ACYCLIC AMINOPHOSPHINES

Tris(dimethylamino)phosphine (IIIa) and/or bis-dimethylaminophenyl-phosphine (IIIb) react with 9,10-dihydro(9-dicyanomethylene)phenanthrene-10-one (Ib) to produce 1:1 adducts which have the aminophosphonium dipolar ion structure (V) in the crystalline state and in solutions.The 1:1 adduct isolated from the reaction of IIIb with 9,10-phenanthrenequinonenmonoimine (Ic) has a similar dipolar structure (XII) in the crystalline state.Solutions of the latter contained the same molecular species (XII) in equilibrium with a cyclic aminophospholene species (XIII).Only decomposition products could be observed from the reaction of IIIa with Ic.The products in this case were the phosphoroamidate (X), 9,10-phenanthrenequinone (Ia) and phenanthroxazine XI.A mechanism is proposed to explain the formation of these compounds.Key words: Tris(dimethylamino)phosphine (IIIa); bis-(dimethylamino)-phenyl-phosphine (IIIb); 9,10-dihydro(9-dicyanomethylene)phenanthrene-10-one (Ib); 9,10-phenanthrenequinonemonoimine (Ic); phosphonium dipolar ions (V, XII); cyclic aminophospholene ring system (XIII); phenanthroxazine (XI); hexamethylphosphoroamidate (X).