1376282-63-1Relevant academic research and scientific papers
Iron-Catalyzed Synthesis of α-Dienyl Five- and Six-Membered N-Heterocycles
Gonnard, Laurine,Guérinot, Amandine,Cossy, Janine
, p. 6160 - 6167 (2017/11/15)
The iron-catalyzed synthesis of α-dienyl N-heterocycles is reported. The method is cost-effective, atom-economic, and led to a range of substituted α-dienyl heterocycles in moderate to good yields and diastereoselectivities. The α-dienyl piperidines are key synthetic intermediates as demonstrated by the preparation of a panel of α-polyenyl N-heterocycles.
Mg(ClO4)2-catalyzed intramolecular allylic amination: Application to the total synthesis of demethoxyfumitremorgin C
Jiang, Danfeng,Xu, Zhengren,Jia, Yanxing
, p. 4225 - 4232 (2012/07/14)
A Mg(ClO4)2-catalyzed intramolecular amination of allylic alcohols with carbamate or sulfonamide nucleophiles to form substituted piperidine and pyrrolidine derivatives has been developed. This method has been successfully applied to the total synthesis of demethoxyfumitremorgin C.
