1376520-70-5Relevant academic research and scientific papers
Bi(OTf)3-catalyzed cycloisomerization of aryl-allenes
Lemiere, Gilles,Cacciuttolo, Bastien,Belhassen, Emilie,Dunach, Elisabet
supporting information; experimental part, p. 2750 - 2753 (2012/08/07)
Intramolecular hydroarylation of allenes was achieved under very mild conditions using bismuth(III) triflate as the catalyst. Efficient functionalization of activated and nonactivated aromatic nuclei led to C-C bond formation through a formal Ar-H activation. A tandem bis-hydroarylation of the allene moiety was also developed giving access to various interesting polycyclic structures.
