137679-04-0Relevant academic research and scientific papers
SAMARIUM(II) IODIDE PROMOTED RADICAL RING OPENING REACTIONS OF CYCLOPROPYL KETONES
Batey, Robert A.,Motherwell, William B.
, p. 6649 - 6652 (2007/10/02)
Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy.The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.Key Words: Samarium(II) Iodide Reduction; Cyclopropylcarbinyl Radical Rearrangement; Cyclopropyl Ketone; Radical Cyclisation; Samarium Enolate.
Samarium(II) iodide promoted radical ring opening reactions of cyclopropyl ketones
Batey,Motherwell
, p. 6211 - 6214 (2007/10/02)
Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy. The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.
