137696-31-2

Upstream product

• 137696-30-1 <1S-(exo,exo)>-4,7,7-Trimethyl-3-(1-naphthyl)bicyclo<2.2.1>heptan-2-yl 3(R)-hydroxy-(E,E)-4,6-dodecadienoate 
• 25152-84-5 trans,trans-2,4-decadienal 

Downstream Products

• 137718-38-8 (Z)-7-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxy)-5-oxo-2-((E)-(R)-1-phenylsulfanyl-oct-2-enyl)-cyclopentyl]-hept-5-enoic acid methyl ester 
• 137696-44-7 (5Z,8α,11R,12β,13E,15S)-11-<(tert-Butyldiphenylsilyl)oxy>-9-oxoprosta-5,13-dien-1-oic acid methylester 
• 137696-44-7 (5Z,11R,12β,13E,15S)-11-<(tert-Butyldiphenylsilyl)oxy>-9-oxoprosta-5,13-dien-1-oic acid methylester 
• 137696-42-5 (Z)-7-[(1R,4R,5S,6S)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((E)-hept-1-enyl)-2-oxo-bicyclo[3.1.0]hex-1-yl]-hept-5-enoic acid methyl ester 
• 137696-42-5 Methyl <(1R,4R,5R,7R)-7-<6(E)-heptenyl>-1-oxo-4-<(tert-butyldiphenylsilyl)oxy>bicyclo<3.1.0>hexyl>-1(Z)-δ-heptenoate 
• 137696-35-6 (1R,4R,5S,6S)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((E)-hept-1-enyl)-1-propyl-bicyclo[3.1.0]hexan-2-one 
• 137696-35-6 (1R,4S,5S,6S)-4-(tert-Butyl-diphenyl-silanyloxy)-6-((E)-hept-1-enyl)-1-propyl-bicyclo[3.1.0]hexan-2-one 
• 23453-26-1 (+)-8-epi-Prostaglandin E2 methyl ester 
• 137696-41-4 Methyl 11(R)-<(tert-butyldiphenylsilyl)oxy>-8-diazo-9-oxo-(Z,E,E)-5,12,14-eicosatrienoate 
• 137696-33-4 7-<(tert-Butyldiphenylsilyl)oxy>-4-diazo-(E,E)-8,10-hexadecadien-5-one 
• 137696-34-5 7-<(tert-Butyldiphenylsilyl)oxy>-(Z,E,E)-3,8,10-hexadecatrien-5-one 
• 137696-32-3 3(R)-<(tert-Butyldiphenylsilyl)oxy>-(E,E)-4,6-dodecadienoic acid 

Relevant academic research and scientific papers

Enantioselective Rh-Mediated Synthesis of (-)-PGE2 Methyl Ester

Intramolecular Rh(II) carboxylate catalyzed cyclization of an α-diazo β-methylene ketone to form a fused cyclopropane is shown to compete efficiently with β-hydride elimination, so long as a catalyst derived from an electron-donating carboxylate is used.C