Enantioselective Rh-Mediated Synthesis of (-)-PGE2 Methyl Ester

DOI: 10.1021/jo00028a012

Source and publish data:

Journal of Organic Chemistry p. 441 - 447 (1992)

Update date:2022-08-02

Topics:

Authors:

Taber, Douglass F.

Hoerrner, R. Scott

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00028a012

Intramolecular Rh(II) carboxylate catalyzed cyclization of an α-diazo β-methylene ketone to form a fused cyclopropane is shown to compete efficiently with β-hydride elimination, so long as a catalyst derived from an electron-donating carboxylate is used.C

Full text of DOI:10.1021/jo00028a012

Products guided by the article

Product name:3(R)-Hydroxy-(E,E)-4,6-dodecadienoic acid

Cas No:137696-31-2

R&D Labs maybe for 137696-31-2

Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:Suite 501,198 Kaiyuan Ave.,Science City, Guangzhou,China
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.

Contact:+86-15853188990

Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.

Relevant to this article

Structure diversification of vancomycin through peptide-catalyzed, site-selective lipidation: A catalysis-based approach to combat glycopeptide-resistant pathogens

Doi:10.1021/jm501872s
(2015)
Synthesis of unsymmetrically substituted 4,6,10-trihydroxy-1,4,6,10-tetra- azaadamantanes via intramolecular cyclization of tris(-oximinoalkyl)amines

Doi:10.1055/s-0031-1289735
(2012)
Diastereoselective aldol condensation of directly generated titanium enolates of activated esters

Doi:10.1016/S0040-4020(01)81945-1
(1991)
A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO₂Gas over CO Gas in the Solid State

Doi:10.1002/anie.201604730
(2016)
Naturally occurring bioactive 5-ethylidenehydantoins as inspiration for the development of analogues

Doi:10.1080/00397911.2018.1467457
(2018)
Crystal structures, two-photon absorption and theoretical calculation of a series of bis-vinylpyridine compounds synthesized by one-step solid state reaction

Doi:10.1007/s11426-010-4141-6
(2011)

Article Doi