Enantioselective Rh-Mediated Synthesis of (-)-PGE2 Methyl Ester

DOI: 10.1021/jo00028a012

Source and publish data:

Journal of Organic Chemistry p. 441 - 447 (1992)

Update date:2022-08-02

Topics:

Authors:

Taber, Douglass F.

Hoerrner, R. Scott

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00028a012

Intramolecular Rh(II) carboxylate catalyzed cyclization of an α-diazo β-methylene ketone to form a fused cyclopropane is shown to compete efficiently with β-hydride elimination, so long as a catalyst derived from an electron-donating carboxylate is used.C

Full text of DOI:10.1021/jo00028a012

Products guided by the article

Product name:3(R)-Hydroxy-(E,E)-4,6-dodecadienoic acid

Cas No:137696-31-2

R&D Labs maybe for 137696-31-2

Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.

Contact:15857995878 0579-82207761

Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
HOST COUNTRY LIMITED

Contact:+852 83038667

Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
APOLLO HEALTHCARE RESOURCES

Contact:+65 9658 0999

Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971

Relevant to this article

Structure diversification of vancomycin through peptide-catalyzed, site-selective lipidation: A catalysis-based approach to combat glycopeptide-resistant pathogens

Doi:10.1021/jm501872s
(2015)
Synthesis of unsymmetrically substituted 4,6,10-trihydroxy-1,4,6,10-tetra- azaadamantanes via intramolecular cyclization of tris(-oximinoalkyl)amines

Doi:10.1055/s-0031-1289735
(2012)
Diastereoselective aldol condensation of directly generated titanium enolates of activated esters

Doi:10.1016/S0040-4020(01)81945-1
(1991)
A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO₂Gas over CO Gas in the Solid State

Doi:10.1002/anie.201604730
(2016)
Naturally occurring bioactive 5-ethylidenehydantoins as inspiration for the development of analogues

Doi:10.1080/00397911.2018.1467457
(2018)
Crystal structures, two-photon absorption and theoretical calculation of a series of bis-vinylpyridine compounds synthesized by one-step solid state reaction

Doi:10.1007/s11426-010-4141-6
(2011)

Article Doi