Enantioselective Rh-Mediated Synthesis of (-)-PGE2 Methyl Ester

DOI: 10.1021/jo00028a012

Source and publish data:

Journal of Organic Chemistry p. 441 - 447 (1992)

Update date:2022-08-02

Topics:

Authors:

Taber, Douglass F.

Hoerrner, R. Scott

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00028a012

Intramolecular Rh(II) carboxylate catalyzed cyclization of an α-diazo β-methylene ketone to form a fused cyclopropane is shown to compete efficiently with β-hydride elimination, so long as a catalyst derived from an electron-donating carboxylate is used.C

Full text of DOI:10.1021/jo00028a012

Products guided by the article

Product name:3(R)-Hydroxy-(E,E)-4,6-dodecadienoic acid

Cas No:137696-31-2

R&D Labs maybe for 137696-31-2

Changzhou Yongxu Chemical Co.,Ltd

Contact:86-0519-85286591

Address:Room 1812,Wanda Plaza B,Xinbei District,Changzhou,Jiangsu,China
Xinjiang Fufeng Biotechnologies Co., Ltd.

Contact:+86-539-7287111

Address:GANQUANPU INDUSTRIAL PARK, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT AREA (TOUTUNHE DISTRICT) OF URUMQI
Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Xi'an HO-SHINE Bio-Technology Co., Ltd

Contact:+86 (29) 8248-5435/18292020086

Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China

Relevant to this article

Structure diversification of vancomycin through peptide-catalyzed, site-selective lipidation: A catalysis-based approach to combat glycopeptide-resistant pathogens

Doi:10.1021/jm501872s
(2015)
Synthesis of unsymmetrically substituted 4,6,10-trihydroxy-1,4,6,10-tetra- azaadamantanes via intramolecular cyclization of tris(-oximinoalkyl)amines

Doi:10.1055/s-0031-1289735
(2012)
Diastereoselective aldol condensation of directly generated titanium enolates of activated esters

Doi:10.1016/S0040-4020(01)81945-1
(1991)
A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO₂Gas over CO Gas in the Solid State

Doi:10.1002/anie.201604730
(2016)
Naturally occurring bioactive 5-ethylidenehydantoins as inspiration for the development of analogues

Doi:10.1080/00397911.2018.1467457
(2018)
Crystal structures, two-photon absorption and theoretical calculation of a series of bis-vinylpyridine compounds synthesized by one-step solid state reaction

Doi:10.1007/s11426-010-4141-6
(2011)

Article Doi