Enantioselective Rh-Mediated Synthesis of (-)-PGE2 Methyl Ester

DOI: 10.1021/jo00028a012

Source and publish data:

Journal of Organic Chemistry p. 441 - 447 (1992)

Update date:2022-08-02

Topics:

Authors:

Taber, Douglass F.

Hoerrner, R. Scott

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Article abstract of DOI:10.1021/jo00028a012

Intramolecular Rh(II) carboxylate catalyzed cyclization of an α-diazo β-methylene ketone to form a fused cyclopropane is shown to compete efficiently with β-hydride elimination, so long as a catalyst derived from an electron-donating carboxylate is used.C

Full text of DOI:10.1021/jo00028a012

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