137715-73-2Relevant articles and documents
Verbindungen des Germaniums und Zinns. IX. Ein Stannacyclobuten aus einem sterisch ueberladenen Chlor(mesityl)stannan
Weidenbruch, Manfred,Schaefers, Karen,Schlaefke, Josephin,Peters, Karl,Schnering, Hans Georg von
, p. 343 - 348 (2007/10/02)
Reaction of trichloro(mesityl)stannane with 2,4,6-tri-t-butylphenyllithium (ArLi) in a 1/2 molar ratio, by rearrangement of one aryl group leads to chloro(mesityl)-2,4,6-tri-t-butylphenyl-stannane (3).Treatment of 3 with t-butyllithium gives the sterically congested stannacyclobutene derivative 4 which is fully characterized including an X-ray structure analysis.