137742-71-3Relevant academic research and scientific papers
N-Fluorobisimides: Reactions with Some Olefins via α-Fluoro Carbocationic Intermediates
DesMarteau, Darryl D.,Xu, Ze-Qi,Witz, Michael
, p. 629 - 635 (2007/10/02)
N-Fluorobisimides are a new class of electrophilic fluorinating agents.Reaction of (CF3SO2)2NF (1) with olefins gave various products, depending on the reaction conditions and the structure of the substrate.In solvents of higher nucleophilicity such as H2O, acetic acid, aqueous HCl, and (HF)nPy, α-fluorohydrins and their acetates, α,β-chlorofluoro- and α,β-difluoroalkanes were obtained.In acetic acid, trans-stilbene and tetraphenylethylene produced the rearranged, nonfluorinated aldehyde and ketone.Evidence is presented for the reactions proceeding via a one-electron transfer mechanism involving α-fluorocarbocationic intermediates.
Acetyl Hypofluorite, the First Member of a New Family of Organic Compounds
Rozen, Shlomo,Lerman, Ori,Kol, Moshe
, p. 443 - 444 (2007/10/02)
Some sodium salts in acetic acid-Freon 11 (CFCl3) when treated with elemental fluorine produce acetyl hypofluorite, CH3CO2F, a new electrophilic fluorinating agent.
