137776-40-0

Upstream product

• 130838-75-4 [(R)-1-((S)-2-Benzyloxy-2-[1,3]dithian-2-yl-1,1-dimethyl-ethyl)-2-ethoxy-allyloxy]-tert-butyl-dimethyl-silane 

Downstream Products

• 137776-54-6 (R)-2-Benzyloxy-3-methyl-3-((2S,3S)-3-methyl-oxiranyl)-butyric acid methyl ester 
• 137776-42-2 (3S,5S,6R)-3-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4,6-trimethyl-tetrahydro-pyran-2-one 
• 137776-41-1 (1S,2S,3S,5S)-3-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-1,4,4-trimethyl-cyclopentane-1,2-diol 
• 137776-54-6 (S)-2-Benzyloxy-3-methyl-3-((2S,3S)-3-methyl-oxiranyl)-butyric acid methyl ester 
• 137776-42-2 (3R,5S,6R)-3-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-4,4,6-trimethyl-tetrahydro-pyran-2-one 
• 137776-41-1 (1S,2S,3R,5S)-3-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-1,4,4-trimethyl-cyclopentane-1,2-diol 

Relevant academic research and scientific papers

INTRAMOLECULAR Sm2+ AND Sm3+ PROMOTED REACTION OF γ-OXY-δ-KETOALDEHYDE; STEREOCONTROLLED FORMATION OF PINACOL AND LACTONE

Samarium promoted intramolecular pinacol coupling and Tishchenko oxidoreduction of γ-oxy-δ-ketoaldehyde proceeded stereospecifically.Newly forming hydroxy group is oriented anti to γ-silyloxy group in both reactions.