137776-42-2

Upstream product

• 130838-75-4 [(R)-1-((S)-2-Benzyloxy-2-[1,3]dithian-2-yl-1,1-dimethyl-ethyl)-2-ethoxy-allyloxy]-tert-butyl-dimethyl-silane 
• 137776-40-0 (2S,4R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-5-oxo-hexanal 
• 137776-40-0 (2R,4R)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-5-oxo-hexanal 

Downstream Products

• 137776-54-6 (S)-2-Benzyloxy-3-methyl-3-((2S,3S)-3-methyl-oxiranyl)-butyric acid methyl ester 
• 137776-54-6 (R)-2-Benzyloxy-3-methyl-3-((2S,3S)-3-methyl-oxiranyl)-butyric acid methyl ester 

Relevant academic research and scientific papers

INTRAMOLECULAR Sm2+ AND Sm3+ PROMOTED REACTION OF γ-OXY-δ-KETOALDEHYDE; STEREOCONTROLLED FORMATION OF PINACOL AND LACTONE

Samarium promoted intramolecular pinacol coupling and Tishchenko oxidoreduction of γ-oxy-δ-ketoaldehyde proceeded stereospecifically.Newly forming hydroxy group is oriented anti to γ-silyloxy group in both reactions.