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137777-05-0

1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 137777-05-0 Structure

  • Basic information

    1. Product Name: 1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester
    2. Synonyms:
    3. CAS NO:137777-05-0
    4. Molecular Formula: C11H11NO3
    5. Molecular Weight: 205.213
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 137777-05-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester(137777-05-0)
    11. EPA Substance Registry System: 1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester(137777-05-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 137777-05-0(Hazardous Substances Data)

137777-05-0 Usage

General Description

1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester is a chemical compound with the molecular formula C11H11NO3. It is an ester derivative of pyrrole carboxylic acid, with a cyclohexen-1-yl group attached to the carboxylic acid functionality. 1H-Pyrrole-2-carboxylic acid, 3-oxo-1-cyclohexen-1-yl ester is commonly used in organic synthesis as a building block for the preparation of various pharmaceuticals and biologically active molecules. It has potential applications in medicinal chemistry and drug discovery, and its unique structure makes it a valuable intermediate for the synthesis of complex organic compounds. Additionally, it may have potential biological activities that make it of interest for further research and development in the pharmaceutical industry.

Check Digit Verification of cas no

The CAS Registry Mumber 137777-05-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,7,7,7 and 7 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 137777-05:
(8*1)+(7*3)+(6*7)+(5*7)+(4*7)+(3*7)+(2*0)+(1*5)=160
160 % 10 = 0
So 137777-05-0 is a valid CAS Registry Number.

137777-05-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (3-oxocyclohexen-1-yl) 1H-pyrrole-2-carboxylate

1.2 Other means of identification

Product number -
Other names 1H-Pyrrole-2-carboxylic acid,3-oxo-1-cyclohexen-1-yl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:137777-05-0 SDS

137777-05-0Relevant articles and documents

The cyanide catalyzed isomerization of enol esters derived from cyclic 1,3-diketones

Montes, Imber Flores,Burger, Ulrich

, p. 1007 - 1010 (2007/10/03)

Cross-over experiments unveil that the mechanism of the title reaction consists in cleavage of enol esters by cyanide with transient formation of acyl cyanides. These react as 'soft' C-acylating agents with the enolates freed in the initial step. Use is made of the acyl cyanide derived from pyrrole-2-carboxylic acid to set up the triketide type skeleton 12 of the antibiotic pyoluteorin 16. The aromatization of 12 with mercuric acetate gave the pyrrolo[a]indolone 18.

Rearrangements of Pyrrole and Indole Substituted Enol Esters of Cyclohexane-1,3-dione

Oliver, James E.,Lusby, William R.,Waters, Rolland M.

, p. 1565 - 1568 (2007/10/02)

Enol esters 3a and 3b, from cyclohexane-1,3-dione and pyrrole-2-carbonyl chloride and indole-2-carbonyl chloride, respectively, rearranged in the presence of triethylamine to the enamino acids 7 and 12.In the presence of cyanide, 3b, also underwent the expected rearrangement to 4b, whereas only 7 was formed from 3a.Treatment of 7 with mercuric acetate in hot acetic acid resulted in decarboxylation and aromatization to phenol 9.

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