137787-95-2Relevant academic research and scientific papers
Conformational Analysis of the 16-Membered Epoxyenone and Complete Stereoselection in the Reduction of its C9 Carbonyl Group, the Key Reaction in the Synthesis of Maridonolides
Matsushima, Tomohiro,Nakajima, Noriyuki,Yonemitsu, Osamu,Hata, Tadashi
, p. 4525 - 4532 (1992)
16-membered epoxyenone (2), the key synthetic intermediate of maridonolides, has two distinct conformational isomers in solution.The conformational analysis of them by virtue of NMR measurement and the profound effect of their conformations on reactivity
Two distinct conformational isomers of the 16-membered epoxyenone, the key synthetic intermediate of maridonolides. Conformational analysis and completely stereoselective reduction of the C9 carbonyl group1)
Matsushima, Tomohiro,Nakajima, Noriyuki,Yonemitsu, Osamu,Hata, Tadashi
, p. 5133 - 5136 (2007/10/02)
The key synthetic intermediate of maridonolides (2) has two easily detectable conformational isomers in solution. The conformational analysis of the 16-membered epoxyenone ring and the effect of conformation on reactivity in the reduction of the C9 carbon
