Conformational Analysis of the 16-Membered Epoxyenone and Complete Stereoselection in the Reduction of its C9 Carbonyl Group, the Key Reaction in the Synthesis of Maridonolides

DOI: 10.1016/S0040-4020(01)81225-4

Source and publish data:

Tetrahedron p. 4525 - 4532 (1992)

Update date:2022-08-04

Topics:

Authors:

Matsushima, Tomohiro

Nakajima, Noriyuki

Yonemitsu, Osamu

Hata, Tadashi

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Article abstract of DOI:10.1016/S0040-4020(01)81225-4

16-membered epoxyenone (2), the key synthetic intermediate of maridonolides, has two distinct conformational isomers in solution.The conformational analysis of them by virtue of NMR measurement and the profound effect of their conformations on reactivity

Full text of DOI:10.1016/S0040-4020(01)81225-4

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