137791-25-4Relevant academic research and scientific papers
SIGMATROPIC ISOMERIZATION IN PHOSPHORYLATED 2-AZAALLYLIC SYSTEMS. IX. REGIOSELECTIVITY AND 1,3-TRANSFER OF THE DITHIOPHOSPHORYL GROUP IN REACTIONS OF N-BENZYLIDENE-2,2,2-TRIFLUORO-1-CHLOROETHYLAMINE WITH THIO- AND DITHIOPHOSPHORYL COMPOUNDS
Onys'ko, P. P.,Suvalova, E. A.,Chudakova, T. I.,Sinitsa, A. D.
, p. 763 - 766 (2007/10/02)
In contrast to thiolate anions, nucleophilic thio- and dithiophosphoryl compounds react with N-benzylidene-2,2,2-trifluoro-1-chloroethylamine at the sp3 carbon atom rather than at the sp2 carbon atom of the 2-azaallyl triad.In the presence of triethylamine 1,3-tranfer of the O,O-diethyldithiophosphato and diphenyldithiophosphinato groups in the C=N-C triad is observed.
