88708-76-3Relevant academic research and scientific papers
Synthesis of fluorinated imines and carbodiimides from azides via aza-Wittig reaction
Wu, Yongming,Sun, Qingrui,Deng, Juan,Tian, Weisheng
, p. 1152 - 1157 (2008/03/28)
The Staudinger reaction of fluoroalkylazides were studied. A series of N-fluoroalkylimines were synthesized via aza-Wittig reaction of N-fluoroalkyliminophosphoranes. The N,N′-difluoroalkylated carbodiimide was also synthesized via the reaction of N-fluor
Kinetic stability of novel nitrile ylides
Hegarty, Anthony F.,Eustace, Stephen J.,Tynan, Nuala M.,Pham-Tran, Nguyen-Nguyen,Nguyen, Minh Tho
, p. 1239 - 1246 (2007/10/03)
A series of relatively stable novel trifluoromethyl substituted nitrile ylides have been generated by base promoted elimination of hydrogen chloride from the corresponding imidoyl chlorides in acetonitrile and aqueous dioxane solution at 25 °C. The format
ISOMERIZATION OF TRIFLUOROACETIMIDOYL CHLORIDES AND THEIR 1,3-DIPOLAR CYCLOADDITIONS WITH ELECTRON-DEFICIENT OLEFINS
Tanaka, Kiyoshi,Daikaku, Hiroki,Mitsuhashi, Keiryo
, p. 1463 - 1464 (2007/10/02)
N-Arylmethyltrifluoroacetimidoyl chlorides isomerize to N-(arylmethylene)-1-chloro-2,2,2-trifluoroethylamines in the presence of triethylamine at room temperature and to the corresponding N-trifluoroethylbenzimidoyl chlorides under more drastic conditions
