13780-63-7Relevant academic research and scientific papers
Preparation, Structures, and Reactions of some Difluorothiophosphonate and Difluoroselenophosphonate Complexes of Platinum(II)
Duncan, J. Andrew S.,Ebsworth, E. A. V.,Gould, Robert O.,Jones, C. Lynn,Rankin, David W. H.,Whitelock, John D.
, p. 1028 - 1033 (1981)
The complexes (X=Cl, Br, or I; Y=S or Se) have been prepared by the reaction of trans- with PF2H(Y).The reactions have been studied at low temperatures using 31P and 19F n.m.r. spectroscopy; the formation of IV/sup
Determination of the Molecular Structure of Difluorophosphine Sulphide by the Combined Analysis of Data from Electron Diffraction, Microwave Spectroscopy, and Liquid Crystal Nuclear Magnetic Resonance Spectroscopy
Blair, Peter D.,Cradock, Stephen,Rankin, David W. H.
, p. 755 - 760 (2007/10/02)
Data relating to the molecular structure of difluorophosphine sulphide, PF2HS, obtained by gasphase electron diffraction (e.d.), microwave spectroscopy (m.w.), and by n.m.r. spectroscopy for a solution in a liquid crystal solvent (l.c.n.m.r.) have been analysed.Results are presented and compared for refinements using e.d. data only, m.w. only, e.d. plus m.w., e.d. plus l.c.n.m.r., and finally with all the data analysed simultaneously.In this last refinement the parameters (rα0) obtained were: r(P-F) 154.6(2), r(P=S) 187.5(3), r(P-H) 141.9(13) pm; FPF 99.1(1), FPS 117.2(2), and HPS 116.4(6) deg.
The Preparation, Properties and Gas-Phase Molecular Structure of Difluoro(germylthio)phosphine
Ebsworth, E. A. V.,Macdonald, E. K.,Rankin, D. W. H.
, p. 221 - 234 (2007/10/02)
Difluoro(germylthio)phosphine, PF2(SGeH3), has been prepared by the reaction of S(PF2)2 with GeH3Cl, and has been characterised by i.r., Raman, n.m.r. and mass spectroscopy.Cleavage reactions with Cl2 and HBr, donor reactions of the phosphorus atom and ex
