137833-36-4Relevant articles and documents
Photo-isomerisations reversibles d'enols dans la serie des triacylmethanes
Couchouron, Benoit,Saint, Jacques Le,Courtot, Pierre
, p. 381 - 384 (2007/10/02)
Interconversions between chelated enolic configurational isomers E and Z take place when equilibrated solutions of enolised triacylmethanes ArCO(RCO)CHCOR' are irradiated.It is concluded that isomerization takes place directly by rotation around the olefinic double bond of the enolic ring after cleavage of the intramolecular hydrogen bond.