137837-67-3

Basic information

• Product Name: Silane, (4-ethenylphenoxy)tris(1-methylethyl)-
• CAS NO: 137837-67-3
• Molecular Formula: C17H28OSi
• Molecular Weight: 276.494
• Mol File: 137837-67-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (4-ethenylphenoxy)tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (4-ethenylphenoxy)tris(1-methylethyl)-(137837-67-3)
• EPA Substance Registry System: Silane, (4-ethenylphenoxy)tris(1-methylethyl)-(137837-67-3)

Safety Data

• Hazardous Substances Data: 137837-67-3(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 123-08-0 4-hydroxy-benzaldehyde 
• 27200-84-6 methyl triphenylphosphonium bromide 
• 211617-68-4 4-(triisopropylsilyloxy)benzaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Relevant articles and documents

An Electroreductive Approach to Radical Silylation via the Activation of Strong Si-Cl Bond

The construction of C(sp3)-Si bonds is important in synthetic, medicinal, and materials chemistry. In this context, reactions mediated by silyl radicals have become increasingly attractive but methods for accessing these intermediates remain limited. We present a new strategy for silyl radical generation via electroreduction of readily available chlorosilanes. At highly biased potentials, electrochemistry grants access to silyl radicals through energetically uphill reductive cleavage of strong Si-Cl bonds. This strategy proved to be general in various alkene silylation reactions including disilylation, hydrosilylation, and allylic silylation under simple and transition-metal-free conditions.

TRANS-1,2-DIPHENYLETHYLENE DERIVATIVES AND NANOSENSORS MADE THEREFROM

Novel trans-1, 2-diphenylethylene derivatives are synthesized which can be used to form nanoparticles-monomer- nanomolecule-receptor nanosensors. These trans-1, 2-diphenyl- ethylene derivatives are soluble in both water and organic solvents, highly fluore