1379003-26-5

Basic information

• Product Name: (E)-2-methyl-1-phenyl-1-(trimethoxysilyloxy)-1-butene
• Synonyms: (E)-2-methyl-1-phenyl-1-(trimethoxysilyloxy)-1-butene
• CAS NO: 1379003-26-5
• Molecular Weight: 282.412
• Mol File: 1379003-26-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-methyl-1-phenyl-1-(trimethoxysilyloxy)-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-methyl-1-phenyl-1-(trimethoxysilyloxy)-1-butene(1379003-26-5)
• EPA Substance Registry System: (E)-2-methyl-1-phenyl-1-(trimethoxysilyloxy)-1-butene(1379003-26-5)

Safety Data

• Hazardous Substances Data: 1379003-26-5(Hazardous Substances Data)

Upstream product

• 2487-90-3 trimethoxysilane 
• 22731-65-3 2-ethyl-1-phenylprop-2-en-1-one 

Relevant articles and documents

Construction of quaternary carbon centers by a base-catalyzed enantioselective aldol reaction and related reactions of trimethoxysilyl enol ethers

The aldol reactions of trimethoxysilyl enol ethers catalyzed by lithium binaphtholate were found to be powerful tools for the construction of quaternary asymmetric carbon centers. The stereoselectivities were greatly affected by the presence of water. Trimethoxysilyl enol ether derived from a cyclic ketone, such as cyclohexanone, was used as a substrate to obtain the anti-adduct preferentially under anhydrous conditions; by contrast, the syn-adduct was preferentially obtained under aqueous conditions with high stereoselectivity. The aldol-Tishchenko reaction of a trimethoxysilyl enol ether derived from acyclic ketones proceeded to give monoacyl 1,3-diol derivatives in high enantioselectivities.