137934-96-4Relevant academic research and scientific papers
Acid Catalyzed Alcoholysis of an Epoxide and Reactions of Products on Contact with Silica Gel
Habermehl, Gerhard G.,Wippermann, Irene
, p. 1421 - 1424 (2007/10/02)
The alcoholysis of epoxide 1 in acidic methanol leads to various products; one of these - hydroxymethoxyketone 7 - rearranges to the isomeric ketone 14 on contact with silica gel. Keywords: Cleavage of Epoxide, Rearrangement
Hypervalent Iodine Oxidation of α,β-Unsaturated Carbonyl Compounds
Tamura, Yasumitsu,Yakura, Takayuki,Terashi, Hiroaki,Haruta, Jun-Ichi,Kita, Yasuyuki
, p. 570 - 577 (2007/10/02)
Oxidation of non-enolizable α,β-unsaturated carbonyl compounds and enolizable β-monosubstituted α,β-unsaturated carbonyl compounds with phenyl iodine(III) diacetate (PIDA) in methanolic potassium hydroxide gave α-hydroxydimethylacetal β-methoxy products,
