1379458-83-9Relevant academic research and scientific papers
Temperature dependence of photosensitized nucleophilic addition to alkenes
Matsumoto, Jin,Yoshinaga, Yusuke,Hamasaki, Akiko,Kawasaki, Tomohiro,Yamashita, Toshiaki,Shiragami, Tsutomu,Yasuda, Masahide
, p. 1130 - 1132 (2011)
Photosensitized nucleophilic additions of 2,5-dimethyl- 2,4-hexadiene and 2,3-dimethyl-2-butene were performed in a microchannel reactor using phenanthrene and p-dicyanobenzene as a redox pair. The quantum yields for the formation of photo-NOCAS products were remarkably enhanced at lower temperatures. The exciplex formation disturbed the reaction at higher temperatures.
