1379459-99-0

Upstream product

• 93296-10-7 (4-(dimethylamino)phenyl)zinc(II) chloride 
• 22325-27-5 4,6-dimethyl-2-meraptopyrimidine 
• 28611-39-4 4-(dimethylamino)benzene-boronic acid 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 16879-40-6 2-iodo-4,6-dimethylpyrimidine 

Downstream Products

• 1379459-62-7 2-(4'-dimethylaminophenyl)-pyrimidine-4,6-dicarboxaldehyde bis(2-pyridyl hydrazone) 
• 1393915-17-7 2-(4'-dimethylaminophenyl)-pyrimidine-4,6-dicarboxaldehyde 

Relevant academic research and scientific papers

Transition-Metal-Free Cross-Coupling of Aryl and Heteroaryl Thiols with Arylzinc Reagents

Cross-coupling of (hetero)arylthiols with arylzinc reagents via C-S cleavage was performed under transition-metal-free conditions. The reaction displays a wide scope of substrates and high functional-group tolerance. Electron-rich and -deficient (hetero)arylthiols and arylzinc reagents can be employed in this transformation. Mg2+ and Li+ ions were demonstrated to facilitate the reaction.

Molecular motion in zinc hydrazone grid complexes

Four new grid forming hydrazone ligands substituted with methoxy and dimethylamino groups were synthesised. Combination of these ligands with zinc triflate in acetonitrile resulted in self-assembly to form grids as indicated by 1H NMR and ES-MS