137960-07-7

Basic information

• Product Name: 3-Oxazolidinecarboxylic acid, 4-[(4-methoxyphenyl)methyl]-2,2-dimethyl-, phenylmethyl ester, (S)-
• CAS NO: 137960-07-7
• Molecular Formula: C21H25NO4
• Molecular Weight: 355.434
• Mol File: 137960-07-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Oxazolidinecarboxylic acid, 4-[(4-methoxyphenyl)methyl]-2,2-dimethyl-, phenylmethyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxazolidinecarboxylic acid, 4-[(4-methoxyphenyl)methyl]-2,2-dimethyl-, phenylmethyl ester, (S)-(137960-07-7)
• EPA Substance Registry System: 3-Oxazolidinecarboxylic acid, 4-[(4-methoxyphenyl)methyl]-2,2-dimethyl-, phenylmethyl ester, (S)-(137960-07-7)

Safety Data

• Hazardous Substances Data: 137960-07-7(Hazardous Substances Data)

Upstream product

• 74-88-4 methyl iodide 
• 761433-72-1 (S)-4-(4-Hydroxy-benzyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid benzyl ester 
• 137960-06-6 (R)-4-(4-Hydroxy-benzoyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid benzyl ester 
• 501-53-1 benzyl chloroformate 
• 40829-66-1 (S)-2-(benzyloxycarbonylamino)-3-(4-hydroxyphenyl)-1-propanol 
• 13512-31-7 N-(benzyloxycarbonyl)-L-tyrosine methyl ester 

Downstream Products

• 115424-05-0 (S)-benzyl (1-hydroxy-3-(4-methoxyphenyl)propan-2-yl)carbamate 
• 761433-74-3 (S)-4-{3-[(3-Bromo-2-methoxymethoxy-phenyl)-hydroxy-methyl]-4-methoxy-benzyl}-2,2-dimethyl-oxazolidine-3-carboxylic acid benzyl ester 
• 761433-98-1 (S)-4-[3-(3-Bromo-2-methoxymethoxy-benzoyl)-4-methoxy-benzyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid benzyl ester 
• 17554-34-6 (2S)-2-[(benzyloxycarbonyl)amino]-3-(4-methoxyphenyl)propanoic acid 
• 761433-73-2 (S)-4-(3-Iodo-4-methoxy-benzyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid benzyl ester 

Relevant articles and documents

Studies toward diazonamide A: Initial synthetic forays directed toward the originally proposed structure

A brief introduction into the chemistry of diazonamide A (1) is followed by first-generation sequences to access the originally proposed structure for this unusual marine natural product. These explorations identified a route capable of delivering a model compound possessing the complete heteroaromatic core of the natural product, highlighting in the process several unanticipated synthetic challenges which led both to new methodology as well as an improved synthetic plan that was successfully applied to fully functionalized intermediates.