1379609-52-5Relevant academic research and scientific papers
Two new metal-organic frameworks based on 5-bromoisophthalic acid and 1,3-bi(4-pyridyl)propane: Hydrothermal syntheses, structures, and magnetic properties
Han, Min-Le,Wu, Hai-Xia,Zhao, Ke-Yan,Zhang, Zu-Qiang
, p. 590 - 595 (2012)
Two new complexes, [M((H2O)(bpp)(Brip)]n (M = Co II (1) and NiII (2), bpp = 1,3-bi(4-pyridyl)propane, H2Brip = 5-bromoisophthalic acid), have been synthesized through hydrothermal reaction. They were characterized by elemental analysis, IR spectra, thermal analysis, magnetic properties, and X-ray single-crystal diffraction. The two complexes belong to monoclinic system, C2/c space group. The adjacent CoII or NiII ions are bridged by Brip to form an alternate 1D chain. Such 1D chains are further connected by bpp to generate a twofold interpenetrating diamondoid 3D network. Variable-temperature magnetic susceptibility measurements indicate the occurrence of weak ferromagnetic interactions between the CoII (1) and NiII (2) ions, respectively. Copyright Taylor & Francis Group, LLC.
