1379662-49-3

Upstream product

• 455288-51-4 4-amino-2,6-diisopropylaniline 
• 140411-20-7 4-iodo-2,6-diisopropylaniline 

Downstream Products

• 1379662-57-3 N,N'-bis(2,6-diisopropyl-4-(4-phenyl-1,2,3-1H-triazol-1-yl)phenyl)imidazolium chloride 
• 1379662-58-4 N,N'-bis(2,6-diisopropyl-4-(4-hydroxymethyl-1,2,3-1H-triazol-1-yl)phenyl)imidazolium chloride 
• 1379662-51-7 N,N'-bis(4-azido-2,6-diisopropylphenyl)imidazolium chloride 
• 1379662-54-0 1,4-bis[2,6-diisopropyl-4-(4-phenyl-1,2,3-1H-triazol-1-yl)phenyl]1,4-diazabuta-1,3-diene 
• 1379662-55-1 1,4-bis[2,6-diisopropyl-4-(4-hydroxymethyl-1,2,3-1H-triazol-1-yl)phenyl]-1,4-diazabuta-1,3-diene 
• 1379662-50-6 1,4-bis(4-azido-2,6-diisopropylphenyl)-1,4-diazabuta-1,3-diene 
• 455288-51-4 4-amino-2,6-diisopropylaniline 

Relevant academic research and scientific papers

Aromatic azido-selective reduction via the staudinger reaction using tri-n-butylphosphonium tetrafluoroborate with triethylamine

An efficient method for the reduction of aromatic azides to anilines via the Staudinger reaction using tri-n-butylphosphonium tetrafluoroborate with triethylamine in aqueous tetrahydrofuran solution is reported. The method enables the aromatic azido-selective reduction of 3-azido-5-(azidomethyl)benzene derivatives to efficiently afford anilines bearing an azidomethyl group.

Access to functionalised silver(I) and gold(I) N-heterocyclic carbenes by [2 + 3] dipolar cycloadditions

A new strategy was developed for the modification of silver(i) and gold(i) N-heterocyclic carbenes. Azido groups were grafted and used either by copper-catalysed azide-alkyne cycloaddition before metallation or by thermal and "strain-promoted" 1,3-dipolar cycloaddition after metallation to functionalise the metal-NHCs.