1379662-57-3Relevant academic research and scientific papers
Access to functionalised silver(I) and gold(I) N-heterocyclic carbenes by [2 + 3] dipolar cycloadditions
Hospital, Audrey,Gibard, Clementine,Gaulier, Christelle,Nauton, Lionel,Thery, Vincent,El-Ghozzi, Malika,Avignant, Daniel,Cisnetti, Federico,Gautier, Arnaud
, p. 6803 - 6812 (2012/07/02)
A new strategy was developed for the modification of silver(i) and gold(i) N-heterocyclic carbenes. Azido groups were grafted and used either by copper-catalysed azide-alkyne cycloaddition before metallation or by thermal and "strain-promoted" 1,3-dipolar cycloaddition after metallation to functionalise the metal-NHCs.
