1379673-45-6

Basic information

• Product Name: 1-phenyl-3-(tributylstannyl)prop-2-yn-1-ol
• Synonyms: 1-phenyl-3-(tributylstannyl)prop-2-yn-1-ol
• CAS NO: 1379673-45-6
• Molecular Weight: 421.21
• Mol File: 1379673-45-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenyl-3-(tributylstannyl)prop-2-yn-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-3-(tributylstannyl)prop-2-yn-1-ol(1379673-45-6)
• EPA Substance Registry System: 1-phenyl-3-(tributylstannyl)prop-2-yn-1-ol(1379673-45-6)

Safety Data

• Hazardous Substances Data: 1379673-45-6(Hazardous Substances Data)

Upstream product

• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 1067-52-3 tributyltin methoxide 
• 99067-61-5 3-chloro-1-phenyl-prop-2-yn-1-ol 
• 1461-22-9 tributyltin chloride 

Relevant articles and documents

Trialkylborane-Mediated Multicomponent Reaction for the Diastereoselective Synthesis of Anti-δ,δ-Disubstituted Homoallylic Alcohols

The trialkylborane/O2-mediated reaction of propargyl acetates having a tributylstannyl group at an alkyne terminus with aldehydes in a THF-H2O solvent system gave anti-δ,δ-disubstituted homoallylic alcohols with good to high diastereoselectivity. Intriguingly, two alkyl groups derived from trialkylborane were embedded into the reaction product. The trialkylborane plays a key role not only as a radical initiator but also as a source of alkyl radicals.

Lithiation of 1,2-dichloroethene in flow microreactors: Versatile synthesis of alkenes and alkynes by precise residence-time control

It′s all about the timing: Precise control of the residence time (tRx; see picture) of reactive intermediates in flow microreactors enables the reaction pathway of lithiated 1,2-dichloroethene to be switched to produce either alkenes or alkynes. This method also allows versatile syntheses of asymmetric disubstituted dichloroalkenes and alkynes. Copyright