99067-61-5

Upstream product

• 79-01-6 Trichloroethylene 
• 100-52-7 benzaldehyde 
• 156-60-5 trans-1,2-dichloroethylene 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 

Downstream Products

• 4482-17-1 1,4-diphenyl-but-2-yne-1,4-diol 
• 1379673-45-6 1-phenyl-3-(tributylstannyl)prop-2-yn-1-ol 
• 1379673-46-7 3-dimethylsilyl-1-phenyl-prop-2-yn-1-ol 
• 131354-47-7 4-methyl-1-phenyl-pent-2-yne-1,4-diol 
• 1235384-23-2 1-(3-hydroxy-3-phenylprop-1-yn-1-yl)cyclohexan-1-ol 

Relevant academic research and scientific papers

Flash chemistry using trichlorovinyllithium: Switching the reaction pathways by high-resolution reaction time control

High-resolution reaction time control in flow microreactors enables the reaction-pathway switching of trichlorovinyllithium generated by the H/Li exchange of trichloroethene. The method was successfully app lied to the synthesis of 1,1,2-trichloroalkenes,

Lithiation of 1,2-dichloroethene in flow microreactors: Versatile synthesis of alkenes and alkynes by precise residence-time control

It′s all about the timing: Precise control of the residence time (tRx; see picture) of reactive intermediates in flow microreactors enables the reaction pathway of lithiated 1,2-dichloroethene to be switched to produce either alkenes or alkynes. This method also allows versatile syntheses of asymmetric disubstituted dichloroalkenes and alkynes. Copyright