1379675-00-9Relevant academic research and scientific papers
Gold-catalyzed oxidative cyclizations of cis-3-En-1-ynes to form cyclopentenone derivatives
Bhunia, Sabyasachi,Ghorpade, Satish,Huple, Deepak B.,Liu, Rai-Shung
supporting information; experimental part, p. 2939 - 2942 (2012/05/20)
Golden tendencies: The title reaction for synthesizing cyclopentenone derivatives utilizes a gold complex and 8-methylquinoline oxide as the catalyst system (see scheme; IPr=1,3-bis(diisopropylphenyl)imidazol-2-ylidene). Such products are not attainable using diazocarbonyl reagents, as the gold carbenoids tend to react with C-H bonds. Copyright
