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1379690-67-1

Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1379690-67-1 Structure

  • Basic information

    1. Product Name: Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN
    2. Synonyms:
    3. CAS NO:1379690-67-1
    4. Molecular Formula:
    5. Molecular Weight: 798.805
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1379690-67-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN(CAS DataBase Reference)
    10. NIST Chemistry Reference: Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN(1379690-67-1)
    11. EPA Substance Registry System: Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN(1379690-67-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1379690-67-1(Hazardous Substances Data)

1379690-67-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1379690-67-1 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,7,9,6,9 and 0 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1379690-67:
(9*1)+(8*3)+(7*7)+(6*9)+(5*6)+(4*9)+(3*0)+(2*6)+(1*7)=221
221 % 10 = 1
So 1379690-67-1 is a valid CAS Registry Number.

1379690-67-1Downstream Products

1379690-67-1Relevant articles and documents

Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes

Coggins, Michael K.,Toledo, Santiago,Shaffer, Erika,Kaminsky, Werner,Shearer, Jason,Kovacs, Julie A.

, p. 6633 - 6644 (2012)

The synthesis, structural, and spectroscopic characterization of four new coordinatively unsaturated mononuclear thiolate-ligated manganese(II) complexes ([MnII(SMe2N4(6-Me-DPEN))](BF4) (1), [MnII(SMe2N4(6-Me-DPPN))](BPh 4)·MeCN (3), [MnII(SMe2N 4(2-QuinoPN))](PF6)·MeCN·Et2O (4), and [MnII(SMe2N4(6-H-DPEN)(MeOH)](BPh 4) (5)) is described, along with their magnetic, redox, and reactivity properties. These complexes are structurally related to recently reported [MnII(SMe2N4(2-QuinoEN))](PF 6) (2) (Coggins, M. K.; Kovacs, J. A. J. Am. Chem. Soc.2011, 133, 12470). Dioxygen addition to complexes 1-5 is shown to result in the formation of five new rare examples of Mn(III) dimers containing a single, unsupported oxo bridge: [MnIII(SMe2N4(6-Me-DPEN)] 2-(μ-O)(BF4)2·2MeOH (6), [Mn III(SMe2N4(QuinoEN)]2-(μ-O) (PF6)2·Et2O (7), [Mn III(SMe2N4(6-Me-DPPN)]2-(μ-O) (BPh4)2 (8), [MnIII(SMe2N 4(QuinoPN)]2-(μ-O)(BPh4)2 (9), and [MnIII(SMe2N4(6-H-DPEN)] 2-(μ-O)(PF6)2·2MeCN (10). Labeling studies show that the oxo atom is derived from 18O2. Ligand modifications, involving either the insertion of a methylene into the backbone or the placement of an ortho substituent on the N-heterocyclic amine, are shown to noticeably modulate the magnetic and reactivity properties. Fits to solid-state magnetic susceptibility data show that the Mn(III) ions of μ-oxo dimers 6-10 are moderately antiferromagnetically coupled, with coupling constants (2J) that fall within the expected range. Metastable intermediates, which ultimately convert to μ-oxo bridged 6 and 7, are observed in low-temperature reactions between 1 and 2 and dioxygen. Complexes 3-5, on the other hand, do not form observable intermediates, thus illustrating the effect that relatively minor ligand modifications have upon the stability of metastable dioxygen-derived species.

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