1380107-81-2Relevant academic research and scientific papers
Synthesis and unexpected coordination of a silicon(II)-based sicsi pincerlike arene to palladium
Wang, Wenyuan,Inoue, Shigeyoshi,Irran, Elisabeth,Driess, Matthias
supporting information; experimental part, p. 3691 - 3694 (2012/05/20)
SiCSi to pick up a metal: A bis(silylene) SiCSi pincerlike arene 1 (see scheme) has been synthesized through salt metathesis reaction of the dilithium salt of 2,4-di-tert-butyl-resorcinolate with the respective chloro silylene precursor [LSiCl]. Remarkably, 1 reacts with Pd(PPh3)4 in a molar ratio of 2:1 under loss of all phosphine ligands to give the pincer complex 2.
