1380225-68-2Relevant academic research and scientific papers
Efficient bipolar host materials based on carbazole and 2-methyl pyridine for use in green phosphorescent organic light-emitting diodes
Kim, Jwajin,Kim, Se Hyun,Lee, Ho Won,Lee, Song Eun,Kim, Young Kwan,Yoon, Seung Soo
, p. 5548 - 5552 (2015)
Two host materials based on the carbazole/pyridine end-capping group were designed and synthesized to produce green phosphorescent organic light-emitting diodes. One of the host materials, 9-[9,9-diethyl-2-(6-methylpyridin-2-yl)-9H-fluoren-7-yl]-9H-carbaz
A highly efficient and aerobic protocol for the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via a palladium-catalyzed ligand-free Suzuki reaction
Rao, Xiaofeng,Liu, Chun,Qiu, Jieshan,Jin, Zilin
supporting information, p. 7875 - 7883 (2013/06/27)
A palladium-catalyzed aerobic and ligand-free Suzuki reaction in aqueous ethanol has been developed for the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives. A number of N-heteroaryl halides, namely 2-halogenated pyridines, 2-bromoquinoline, 5-bromopyrimidine and 2-chloropyrazine, were coupled with 4-(9H-carbazol-9-yl)phenylboronic acid (CPBA) or 9-phenyl-9H-carbazol-3-ylboronic acid (PCBA) efficiently to afford good to excellent yields in a short reaction time. Moreover, the catalytic system of Pd(OAc)2-EtOH/H2O-K2CO3 was successfully extended to the cross-couplings of N-heteroaryl halides with various arylboronic acids. The results demonstrated that the cross-coupling reaction in the present protocol was promoted by oxygen.
