1380241-42-8

Basic information

• Product Name: C₁₁H₁₁IO
• Synonyms: C₁₁H₁₁IO
• CAS NO: 1380241-42-8
• Molecular Weight: 286.112
• Mol File: 1380241-42-8.mol

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₁IO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₁IO(1380241-42-8)
• EPA Substance Registry System: C₁₁H₁₁IO(1380241-42-8)

Safety Data

• Hazardous Substances Data: 1380241-42-8(Hazardous Substances Data)

Upstream product

• 22273-77-4 ((but-3-yn-1-yloxy)methyl)benzene 

Downstream Products

• 1380241-45-1 (2S,3R)-2-(2-(benzyloxy)ethyl)-3-(prop-1-yn-1-yl)oxirane 
• 1380241-46-2 (3S,4S)-1-(benzyloxy)-4-methylhept-5-yn-3-ol 
• 1380241-34-8 (3S,4S)-1-(benzyloxy)-4-methyl-3-(2-(trimethylsilyl)ethoxymethyloxy)-hept-5-yne 
• 1380241-43-9 (Z)-(((4-iodobut-3-en-1-yl)oxy)methyl)benzene 
• 1380241-44-0 (Z)-((hept-3-en-5-yn-1-yloxy)methyl)benzene 

Relevant articles and documents

Convergent synthesis of deoxypropionates

Metallacycle-mediated allylic alcohol-alkyne reductive cross-coupling is described as a convergent solution to the synthesis of deoxypropionates. This approach offers superior step-economy in comparison to available strategies based on multistep iterative chain elongation. The technique is demonstrated in a concise synthesis of the C1-C11 subunit of borrelidin, and a total synthesis of (-)-vittatalactone. Copyright

Synthesis of Fused Carbazoles by Gold-Catalyzed Tricyclization of Conjugated Diynes via Rearrangement of an N-Propargyl Group

Various N-propargylanilines bearing a conjugated diyne moiety at the 2-position were converted to tetracyclic fused carbazoles by treatment with a homogeneous gold(I) catalyst. This cascade reaction proceeds through indole formation with concomitant rearrangement of the N-propargyl group, intramolecular nucleophilic addition toward the resulting allene moiety, and subsequent hydroalkenylation. This transformation enables a one-pot synthesis of fused carbazoles from readily accessible substrates with 100% atom economy.