1380288-23-2Relevant academic research and scientific papers
Synthesis of hindered anilines: Copper-catalyzed electrophilic amination of aryl boronic esters
Rucker, Richard P.,Whittaker, Aaron M.,Dang, Hester,Lalic, Gojko
supporting information; experimental part, p. 3953 - 3956 (2012/06/04)
No longer a hindrance: Copper-catalyzed electrophilic amination of aryl boronic esters is accomplished under mild reaction conditions using 2.5-5.0 mol % of a catalyst derived from copper tert-butoxide and Xantphos ligand (see scheme). The reaction tolerates a wide range of functional groups and can be used to prepare some of the most hindered anilines made to date. Copyright
