1380546-62-2

Upstream product

• 4551-39-7 2-deuteriobenzoic acid 
• 61147-93-1 3-butyl-1,2-heptadiene 
• 2446-51-7 N-methoxybenzamide 
• 1380546-52-0 2-deuterio-N-methoxybenzamide 
• 43019-96-1 d₂-benzoyl chloride 
• 1268451-51-9 N-methoxybenzamide-2,3,4,5,6-[D]₅ 

Downstream Products

• 1380546-89-3 2-(3-butylhept-2-enyl)-N-methoxy-6-(1-methoxy-4-propylhept-3-en-2-yl)benzamide 
• 1380546-83-7 2,6-bis(3-butylhept-2-enyl)-N-methoxybenzamide 
• 1380546-87-1 2-(3-butylhept-2(Z)-enyl)-N-methoxy-6-(3-phenylhept-2-enyl)benzamide 
• 1380546-93-9 8-(3-butylhept-2-enyl)-4-(cyclohexylidenemethyl)isochroman-1-one 
• 1380546-90-6 2-(3-butylhept-2-enyl)-6-(1-cyclohexylidene-3-hydroxypropan-2-yl)-N-methoxybenzamide 

Relevant academic research and scientific papers

Room-temperature synthesis of trisubstituted allenylsilanes via regioselective c-h functionalization

A Rh(III)-catalyzed o-C-H bond functionalization-based allenylation reaction of allenylsilanes 2 with N-methoxybenzamides 1 affords poly-substituted allenylsilanes with a wide range of attractive functional groups in moderate to excellent yields under very mild conditions (20 C, compatible with ambient air and moisture). Those products may be transformed to different products with attractive structural features. Careful mechanistic studies suggest the reaction proceeds via o-rhodation, regioselective insertion, and β-H elimination.

Highly selective mild stepwise allylation of N-methoxybenzamides with allenes

An efficient Rh(III)-catalyzed stepwise ortho allylation of N-methoxybenzamides 1 with polysubstituted allenes is reported. This C-H functionalization involving allenes is conducted under very mild conditions (-20 °C or room temperature) and compatible wi