1380546-62-2Relevant articles and documents
Room-temperature synthesis of trisubstituted allenylsilanes via regioselective c-h functionalization
Zeng, Rong,Wu, Shangze,Fu, Chunling,Ma, Shengming
, p. 18284 - 18287 (2013)
A Rh(III)-catalyzed o-C-H bond functionalization-based allenylation reaction of allenylsilanes 2 with N-methoxybenzamides 1 affords poly-substituted allenylsilanes with a wide range of attractive functional groups in moderate to excellent yields under very mild conditions (20 C, compatible with ambient air and moisture). Those products may be transformed to different products with attractive structural features. Careful mechanistic studies suggest the reaction proceeds via o-rhodation, regioselective insertion, and β-H elimination.