1380546-52-0

Basic information

• Product Name: 2-deuterio-N-methoxybenzamide
• Synonyms: 2-deuterio-N-methoxybenzamide
• CAS NO: 1380546-52-0
• Molecular Weight: 152.157
• Mol File: 1380546-52-0.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-deuterio-N-methoxybenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-deuterio-N-methoxybenzamide(1380546-52-0)
• EPA Substance Registry System: 2-deuterio-N-methoxybenzamide(1380546-52-0)

Safety Data

• Hazardous Substances Data: 1380546-52-0(Hazardous Substances Data)

Upstream product

• 71320-95-1 hepta-1,2-dien-3-yltrimethylsilane 
• 2446-51-7 N-methoxybenzamide 
• 43019-96-1 d₂-benzoyl chloride 
• 593-56-6 N-methoxylamine hydrochloride 
• 22069-99-4 1-bromo-2-deuterobenzene 
• 583-55-1 1-Bromo-2-iodobenzene 
• 615-36-1 2-bromoaniline 

Downstream Products

• 1380546-93-9 8-(3-butylhept-2-enyl)-4-(cyclohexylidenemethyl)isochroman-1-one 
• 1380546-83-7 2,6-bis(3-butylhept-2-enyl)-N-methoxybenzamide 
• 1380546-87-1 2-(3-butylhept-2(Z)-enyl)-N-methoxy-6-(3-phenylhept-2-enyl)benzamide 
• 1380546-89-3 2-(3-butylhept-2-enyl)-N-methoxy-6-(1-methoxy-4-propylhept-3-en-2-yl)benzamide 
• 1380546-90-6 2-(3-butylhept-2-enyl)-6-(1-cyclohexylidene-3-hydroxypropan-2-yl)-N-methoxybenzamide 
• 1380546-62-2 2-(3-butylhept-2-enyl)-N-methoxybenzamide 
• 1394239-89-4 C₁₉H₂₈⁽²⁾HNO₂ 

Relevant articles and documents

One-Pot Synthesis of Fused N,O-Heterocycles through Rh(III)-Catalyzed Cascade Reactions of Aromatic/Vinylic N-Alkoxy- Amides with 4-Hydroxy-2-Alkynoates

A highly efficient and regioselective synthesis of furo[3,4-c]isoquinoline-1,5(3H,4H)-diones and furo[3,4-b]pyridine-2,5(1H,7H)-diones via Rh(III)-catalyzed one-pot cascade reactions of aromatic/vinylic N-alkoxyamides with 4-hydroxy-2-alkynoates is presented. Mechanistically, the formation of the title compounds is triggered by a Rh(III)-catalyzed inert C(sp2)?H bond activation of the amide substrate followed by its [4+2] annulation and lactonization with 4-hydroxy-2-alkynoate featuring with an oxidizing and partially traceless directing group. To the best of our knowledge, this is the first example in which both the furan-2(5H)-one and the pyridin-2(1H)-one scaffolds are constructed in one pot under one set of reaction conditions. Compared with literature methods, notable features of this new protocol include facile formation of bis-heterocyclic scaffolds from readily available acyclic substrates, broad substrate scope with good tolerance of a wide range of functional groups, excellent regioselectivity and high efficiency. (Figure presented.).

Ruthenium(II)-Catalyzed C-H Functionalizations with Allenes: Versatile Allenylations and Allylations

Ruthenium(II)-catalyzed direct C-H functionalization of aromatic compounds with allenes was achieved under exceedingly mild reaction conditions to yield trisubstituted allenes. The reactions of N-methoxybenzamides proceeded smoothly in an isohypsic fashio

Rh-catalyzed oxidizing group-directed ortho C-H vinylation of arenes by vinylstannanes

An efficient method for the synthesis of functionalized vinyl arenes from the reaction of N-methoxybenzamides or N-phenoxyacetamides with vinylstannanes via rhodium(III)-catalyzed C-H activation is described. The application of the methodology for the synthesis of a natural product thalactamine and a 7-membered ring oxepine are also demonstrated.