138075-99-7

Basic information

• Product Name: (2R,4S)-2-vinyl-1,3,2-oxapospholidin-2-one
• CAS NO: 138075-99-7
• Molecular Weight: 265.292
• Mol File: 138075-99-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4S)-2-vinyl-1,3,2-oxapospholidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4S)-2-vinyl-1,3,2-oxapospholidin-2-one(138075-99-7)
• EPA Substance Registry System: (2R,4S)-2-vinyl-1,3,2-oxapospholidin-2-one(138075-99-7)

Safety Data

• Hazardous Substances Data: 138075-99-7(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 102720-25-2 (S)-1-((tert-butyldimethylsilyl)oxy)-3-methylbutan-2-amine 
• 2026-48-4 (S)-valinol 
• 690-12-0 (2-chloroethyl)phosphonic dichloride 
• 42807-42-1 N-benzyl-L-valinol 

Downstream Products

• 138076-00-3 (S)-3-Benzyl-2-(1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-yl-4-isopropyl-[1,3,2]oxazaphospholidine 2-oxide 
• 138076-00-3 (S)-3-Benzyl-2-(1S,2R,4S)-bicyclo[2.2.1]hept-5-en-2-yl-4-isopropyl-[1,3,2]oxazaphospholidine 2-oxide 

Relevant articles and documents

Chiral 2-Vinyl-1,2,3-oxazaphospholidin-2-ones: New Dienophiles for Asymmetric Diels-Alder Reactions

Diels-Alder reactions of chiral dienophiles: (2R,4S)- and (2S,4S)-2-vinyl-1,2,3-oxazaphospholidin-2-ones (3 and 4) derived from (S)-valinol with cyclopentadiene led to mixtures of endo- and exo-adducts with high diastereofacial selectivity (>90percent for