1380825-34-2Relevant academic research and scientific papers
Microwave-Enhanced Coupling of Carboxylic Acids with Liquid Ketones and Cyclic Ethers Using Tetrabutylammonium Iodide/ t-Butyl Hydroperoxide
Macías-Benítez, Pablo,Moreno-Dorado, F. Javier,Guerra, Francisco M.
, p. 6027 - 6043 (2020)
The oxidative coupling of carboxylic acids with liquid ketones and cyclic ethers has been accomplished in minutes using t-butyl hydroperoxide in the presence of tetrabutylammonium iodide under microwave irradiation in the absence of a solvent. In addition to drastically shortening the reaction times, the use of microwaves resulted, in general, in yields equal to or higher than those obtained by conventional heating.
Unexpected copper-catalyzed aerobic oxidative cleavage of C(sp 3)-C(sp3) bond of glycol ethers
Liu, Zhong-Quan,Zhao, Lixing,Shang, Xiaojie,Cui, Zili
supporting information; experimental part, p. 3218 - 3221 (2012/08/07)
An unexpected Cu-catalyzed oxidative cleavage of the C(sp 3)-C(sp3) bond in glycol ethers by using air or molecular oxygen as the terminal stoichiometric oxidant is demonstrated. As a result, the corresponding α-acyloxy ethers and fo
