138174-31-9

Upstream product

• 563-52-0 2-chloro-3-butene 
• 103-26-4 methyl cinnamate 
• 4894-61-5 trans-but-2-enyl chloride 
• 1220528-66-4 (1-methylyclopropyl)methyltributylstannane 
• 80935-06-4 phenyl α-iodoacetate 

Relevant academic research and scientific papers

Substituted butenylindium generated by transmetalation of cyclopropylmethylstannane with indium iodide: Synthesis and characterization of monobutenylindium

Transmetalation between substituted cyclopropylmethylstannanes and indium iodide provided the corresponding mono- and dibutenylindium species. The bulky substituent on a cyclopropyl ring selectively afforded the monobutenylindium species, which allowed th

Preparation and Reactivities of (η3-1- and 2-Trimethylsiloxyallyl)Fe(CO2)NO Complexes. Intermediates Functioning as Equivalents of β- and α-Acyl Carbocations and Acyl Carbanions

(η3-1- and 2-Trimethylsiloxyallyl)Fe(CO)2NO complexes were prepared by the reaction of the corresponding siloxyallylic halides with Bu4N.These complexes reacted with both of carbon nucleophiles and carbon electrophiles preferentially at the less hindered sites of the allylic ligands.In these reactions, (η3-1-trimethylsiloxyallyl)Fe(CO)2NO complexes served as synthetically equivalent synthons for both of β-acyl carbocations and β-acyl carbanions and (η3-2-trimethylsiloxyallyl)Fe(CO)2NO complexes as both of α-acyl carbocations and α-acyl carbanions.The stereochemical courses of the reactions are described.