138213-57-7

Upstream product

• 138213-60-2 C₅₁H₇₆O₁₄SSi 
• 138194-44-2 C₅₁H₈₆O₁₃Si₂ 
• 138194-48-6 C₅₁H₈₈O₁₃Si₂ 
• 138194-37-3 (E)-(2S,3S,5S)-8-(1-Ethoxy-ethoxy)-2-methoxymethoxy-3,5,7-trimethyl-oct-6-en-1-ol 
• 138194-43-1 (1S,2S,4aS,5S,6S,8S,8aR)-2-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-propenyl]-5-methoxymethoxy-1,6,8-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carbaldehyde 
• 138213-58-8 (5S,9S,10R)-7-Dimethoxymethyl-4-methoxy-9-methoxymethoxy-10-[(E)-2-methyl-3-(2-trimethylsilanyl-ethoxymethoxy)-propenyl]-1-oxa-spiro[4.5]deca-3,7-dien-2-one 

Downstream Products

• 138194-45-3 C₄₅H₆₀O₁₃S 
• 76705-48-1 (+)-tetronolide 

Relevant academic research and scientific papers

Total synthesis of tetronolide, the aglycon of tetrocarcins

The first total synthesis of tetronolide (1) has been achieved via coupling of spirotetronate 3 with octahydronaphthalene aldehyde 17 and subsequent macrocyclization of ω-sulfone-α-aldehyde 2, leading to confirmation of the absolute configuration of 1.