138240-07-0Relevant academic research and scientific papers
Aerobic Oxygenation of Olefinic Compounds into the Corresponding α-Hydroxy Ketones Using the Catalyst System of OsO4 and Ni(II) Complex
Takai, Toshihiro,Yamada, Tohru,Mukaiyama, Teruaki
, p. 1499 - 1502 (1991)
In the presence of the catalyst system of OsO4 and bis(3-methyl-2,4-pentanedionato)nickel(II), various olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields with molecular oxygen and an aldehyde.
A Novel Method for Preparation of Glycerol Monoesters from Glycidyl Esters with Molecular Oxygen Catalyzed by Ni(II) Complex
Mukaiyama, Teruaki,Imagawa, Kiyomi,Yamada, Tohru,Takai, Toshihiro
, p. 231 - 234 (2007/10/02)
In the presence of a catalytic amount of bis(3-methyl-2,4-pentanedionato)nickel(II) (Ni(mac)2), various glycidyl esters are converted into the corresponding glycerol monoester derivatives with molecular oxygen in good to high yields.
Regiochemistry of Boron Trifluoride Mediated Hydrolysis of Glycidyl Benzoates
Yoshitake, Makoto,Kobayashi, Hiroyuki,Yamamoto, Makoto,Kohmoto, Shigeo,Yamada, Kazutoshi
, p. 1865 - 1868 (2007/10/02)
Hydrolysis of glycidyl benzoates in the presence of BF3*OEt2 in CH2Cl2 affords regioisomeric triol monobenzoates, their ratios remarkably change depending on the temperature particularly in the reaction of 3,3-dimethylglycidyl benzoate.
