138252-29-6Relevant academic research and scientific papers
Chemistry of insect antifeedants from Azadirachta Indica (Part 15):1 Degradation studies of Azadirachtin leading to C8-C14 bond cleavage
Ley, Steven V.,Lovell, Peter J.,Slawin, Alexandra M. Z.,Smith, Stephen C.,Williams, David J.,Wood, Anthony
, p. 1675 - 1700 (1993)
The synthesis of a novel macrocyclic carbonate (5) is described which undergoes a base mediated retro-Aldol reaction to cleave the C8-C14 bond giving the highly functionalised decalin unit (7). This key reaction has allowed the preparation of further deri
Chemistry of insect antifeedants from Azadirachta indica (part 9): Oxidative reactions of azadirachtin derivatives leading to C8-C14 bond cleavage
Ley, Steven V.,Lovell, Peter J.,Smith, Stephen C.,Wood, Anthony
, p. 6183 - 6186 (2007/10/02)
A novel macrocyclic carbonate (4) was obtained by pyridinum chlorochromate oxidation of an azadirachtin derivative (3). This underwent efficient C8-C14 bond cleavage via a retro-Aldol reaction to give a highly functionalised decalin derivative (5) with po
