13827-44-6Relevant academic research and scientific papers
An efficient catalytic and solvent-free method for the synthesis of mono-organofunctionalized 1,1,3,3-tetramethyldisiloxane derivatives
Januszewski, Rafa?,Kownacki, Ireneusz,Maciejewski, Hieronim,Marciniec, Bogdan
, p. 263 - 268 (2017)
Selective mono-functionalization of 1,1,3,3-tetramethyldisiloxane (TMDSO) with olefins via hydrosilylation reaction is reported. On the basis of a study of platinum- and rhodium complexes in the reactions between TMDSO and selected olefins containing C=C bond, it was possible to choose the most efficient catalyst whose application in the solvent-free system led to selective mono-functionalization of the disiloxane reagent and simultaneous formation of only β-regioisomeric products, bearing in their structure functional groups of unique reactivity or physicochemical properties.
An efficient method for synthesizing monofunctionalized derivatives of 1,1,3,3-tetramethyldisiloxane in ionic liquids as recoverable solvents for rhodium catalyst
Kukawka,Januszewski,Kownacki,Smiglak,Maciejewski
, p. 59 - 63 (2018)
Functionalized siloxanes, as one of the most important classes of organosilicon compounds, are widely applied in industry. In our studies, we have investigated, the reaction between 1,1,3,3-tetramethyldisiloxane (TMDSO) and 1-octene, using the rhodium cat
