138290-96-7Relevant academic research and scientific papers
Selective Isomerization of Glycidates and Their Analogues with Triphenylsilyl Perchlorate or Electrogenerated Acid
Inokuchi, Tsutomu,Kusumoto, Masahiko,Matsumoto, Sigeaki,Okada, Hiroyuki,Torii, Sigeru
, p. 2009 - 2012 (1991)
Isomerization of glycidic esters and nitriles to the corresponding 2-hydroxy-3-alkenoates and their nitrile derivatives occurred on treatment with triphenylsilyl perchlorate or electrogenerated acid (EG acid).The cyanohydrin moiety of the nitriles 4 was transformed to a formyl group, giving the corresponding enals on treatment with weak base.
