Chemistry Letters p. 2009 - 2012 (1991)
Update date:2022-07-30
Topics:
Inokuchi, Tsutomu
Kusumoto, Masahiko
Matsumoto, Sigeaki
Okada, Hiroyuki
Torii, Sigeru
Isomerization of glycidic esters and nitriles to the corresponding 2-hydroxy-3-alkenoates and their nitrile derivatives occurred on treatment with triphenylsilyl perchlorate or electrogenerated acid (EG acid).The cyanohydrin moiety of the nitriles 4 was transformed to a formyl group, giving the corresponding enals on treatment with weak base.
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