138307-07-0Relevant academic research and scientific papers
The use of chiral BINAM NHC-Rh(III) complexes in enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters
Xu, Qin,Gu, Xingxing,Liu, Sijia,Dou, Qinyu,Shi, Min
, p. 2240 - 2242 (2007)
Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh-(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters. The reduction products 3-hydroxy-3-arylpropionic acid methyl or ethyl esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions.
Steric effects in the enantioselective transfer hydrogenation of 2- aroylacetates
Everaere, Kathelyne,Carpentier, Jean-Francois,Mortreux, Andre,Bulliard, Michel
, p. 4663 - 4666 (2007/10/03)
Benzoylacetate esters and aryl-substituted derivatives are efficiently reduced in 2-propanol using the readily available catalytic combination (1S,2R)-ephedrine/[RuCl2(η6-p-cymene)]2 to give the corresponding alcohols in high yields and enantioselectivities (up to 94% ee). (C) 2000 Elsevier Science Ltd.
Enantioselective Synthesis of β-Hydroxy Esters by Indium-induced Reformatsky Reaction
Johar, Perminder S.,Araki, Shuki,Butsugan, Yasuo
, p. 711 - 714 (2007/10/02)
Indium-induced Reformatsky reaction, with stoicheiometric amounts of chiral amino alcohols such as cinchonine and cinchonidine, gave optically active β-hydroxy esters in 40-70 percent e.e.
