Cas 138332-59-9,(S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

138332-59-9

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Basic information

Product Name: (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron
Synonyms:
CAS NO:138332-59-9
Molecular Formula:
Molecular Weight: 732.641
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron(CAS DataBase Reference)
NIST Chemistry Reference: (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron(138332-59-9)
EPA Substance Registry System: (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron(138332-59-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 138332-59-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 138332-59-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,8,3,3 and 2 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 138332-59:
(8*1)+(7*3)+(6*8)+(5*3)+(4*3)+(3*2)+(2*5)+(1*9)=129
129 % 10 = 9
So 138332-59-9 is a valid CAS Registry Number.

138332-59-9Upstream product

138259-99-1 ((C₁₀H₆)2(CH₂)2C₅H₃)Fe(CO)2CH₃

138332-59-9Downstream Products

138332-59-9Relevant academic research and scientific papers

Asymmetric migratory insertion reactions of the chiral [(binaphthyldiyldimethylene)cyclopentadienyl]iron complex (BpDMCp)Fe(CO)2CH3

Colletti, Steven L.,Halterman, Ronald L.

, p. 980 - 983 (2008/10/08)

The migratory insertion reaction of a (cyclopentadienyl)methyliron dicarbonyl 2 containing the chiral (binaphthyldiyldimethylene)cyclopentadienyl ligand 1 in the presence of triphenylphosphine can proceed with modest diastereoselectivity. The resulting acyliron complexes 5 are separable and are configurationally stable under oxidative conditions.

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