138356-04-4Relevant academic research and scientific papers
C-Alkylation and N-Acylation of 4-Amino-1-azabutadiene Derivatives. A Convenient Route to Monoalkylated 1,3-Diketones
Barluenga, Jose,Jardon, Jesus,Gotor, Vicente
, p. 802 - 804 (2007/10/02)
Alkylation of 4-amino-1-azabutadiene derivatives 1 with different alkyl halides followed by acid hydrolysis gives mono-C-alkylated 1,3-diketones 3 in excellent yields.In contrast acylation of 1 occurs at the imine nitrogen.
An Unambiguous Synthesis of Pyrazoles by Sulphur Extrusion from 1,2,6-Thiadiazines
Barluenga, Jose,Lopez-Ortiz, J. Francisco,Tomas, Miguel,Gotor, Vicente
, p. 1891 - 1895 (2007/10/02)
Di-imines (1) react with thionyl chloride and sulphur monochloride and dichloride giving different 1,2,6-thiadiazine S-oxides (3) and 1,2,6-thiadiazines (4), respectively.These last two compounds lead, by heating, to pyrazoles (6) via thermal extrusion of
