1383677-49-3Relevant academic research and scientific papers
Iron-catalyzed esterification of allylic sp3 C–H bonds with carboxylic acids: Facile access to allylic esters
Lu, Bing,Zhu, Fan,Wang, Dan,Sun, Hongmei,Shen, Qi
supporting information, p. 2490 - 2494 (2017/05/31)
The first general and efficient iron-catalyzed esterification of allylic sp3 C–H bonds with carboxylic acids using ionic iron(III) complexes (1–4) as a catalyst and DTBP (DTBP?=?di-tert-butyl peroxide) as an oxidant is achieved. A variety of allylic esters were synthesized in good to excellent yields using the ionic iron(III) complex 2 as a catalyst in a 5?mol% loading. This reaction is characterized by its high efficiency, broad substrate scope with excellent steric hindrance tolerance and good functional group compatibility.
Copper-catalyzed esterification of alkylbenzenes with cyclic ethers and cycloalkanes via C(sp3)-H activation following cross-dehydrogenative coupling
Rout, Saroj Kumar,Guin, Srimanta,Ali, Wajid,Gogoi, Anupal,Patel, Bhisma K.
supporting information, p. 3086 - 3089 (2014/06/23)
A copper-catalyzed cross-dehydrogenative coupling strategy has been developed for the synthesis of two classes of esters from simple solvents. The reaction of methylarenes with cyclic ethers resulted in α-acyloxy ethers involving four sp3 C-H cleavages, while treatment of methylarenes with cycloalkanes led to the formation of allyl esters at the expense of six consecutive sp3 C-H bonds.
Tetrabutylammonium iodide catalyzed synthesis of allylic ester with tert -butyl hydroperoxide as an oxidant
Shi, Erbo,Shao, Ying,Chen, Shulin,Hu, Huayou,Liu, Zhaojun,Zhang, Jie,Wan, Xiaobing
supporting information; experimental part, p. 3384 - 3387 (2012/08/08)
A metal-free C-H oxidation for the construction of allylic esters has been developed. The use of a commercially available and inexpensive catalyst and oxidant, and readily available starting materials, coupled with the operational simplicity of the reacti
