138371-96-7

Basic information

• Product Name: tert-butyl 2-(2-oxo-2-phenylethyl)piperidine-1-carboxylate
• Synonyms: tert-butyl 2-(2-oxo-2-phenylethyl)piperidine-1-carboxylate
• CAS NO: 138371-96-7
• Molecular Weight: 303.401
• Mol File: 138371-96-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: tert-butyl 2-(2-oxo-2-phenylethyl)piperidine-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 2-(2-oxo-2-phenylethyl)piperidine-1-carboxylate(138371-96-7)
• EPA Substance Registry System: tert-butyl 2-(2-oxo-2-phenylethyl)piperidine-1-carboxylate(138371-96-7)

Safety Data

• Hazardous Substances Data: 138371-96-7(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 119910-09-7 N-tert-butoxycarbonyl-2-ethoxypiperidine 
• 66324-10-5 tert-butyldimethyl(1-phenylvinyloxy)silane 
• 123387-55-3 1-t-butoxycarbonyl-2-tributylstannylpiperidine 
• 195964-51-3 tert-butyl 2-methoxypiperidine-1-carboxylate 
• 85908-96-9 2-oxopiperidine-1-carboxylic acid tert-butyl ester 
• 132205-80-2 dimethyl phosphonate 
• 157634-02-1 tert-butyl 2-formylpiperidine-1-carboxylate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 30800-90-9 1-phenyl-2-(piperidin-2-yl)ethan-1-one 
• 536-74-3 phenylacetylene 
• 91951-58-5 tert-butyl (tetrahydro-2H-pyran-2-yl)carbamate 

Downstream Products

• 7773-46-8 2-(1-methylpiperidin-2-yl)-1-phenylethan-1-ol 
• 495-47-6 (±)-norsedamine 
• 497-88-1 sedamine 
• 30800-90-9 1-phenyl-2-(piperidin-2-yl)ethan-1-one 
• 138371-97-8 (1RS,2SR) N-tert-butoxycarbonyl-2-(β-hydroxy-β-phenylethyl)piperidine 
• 138371-97-8 (1SR,2SR) N-tert-butoxycarbonyl-2-(β-hydroxy-β-phenylethyl)piperidine 

Relevant articles and documents

Oxidative Generation of N-Acyliminium Ions from N-1-(Tributylstannyl)alkyl Carboxamides and Carbamates and Their Reactions with Carbon Nucleophiles

Oxidation of N-1-(tributylstannyl)alkyl carboxamides and carbamates with ammonium hexanitratocerate (IV) or ferrocenium hexafluorophosphate generates their N-acyliminium ions by the elimination of tributylstannyl radical under mild reaction conditions.The

Gold(I)/(III)-catalyzed synthesis of 2-substituted piperidines; valency-controlled cyclization modes

Strategic use of hard gold(III) and soft gold(I) catalysts provides facile access to two types of 2-substituted piperidines from propargylic alcohols. Thus, heating propargylic alcohols in the presence of AuBr3 results in cyclization to furnish

Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: Applications to the total synthesis of alkaloids

Enantioselective syntheses of the alkaloids (-)-aurantioclavine, (+)-amurensinine, (-)-lobeline, and (-)- and (+)-sedamine are described. The syntheses demonstrate the effectiveness of the Pd-catalyzed asymmetric oxidation of secondary alcohols in diverse contexts and the ability of this methodology to set the absolute configuration of multiple stereocenters in a single operation. The utility of an aryne C-C insertion reaction in accessing complex polycyclic frameworks is also described.

Addition of activated olefins to cyclic N-acyliminium ions in ionic liquids

Organoindate(III) ionic liquid (BMI?InCl4) was successfully employed in the nucleophilic addition of allyltrimethylsilane, silyl enol ethers and ketene silyl acetals to in situ generated cyclic N-acyliminium ions at room temperature without the